全文获取类型
收费全文 | 2210篇 |
免费 | 305篇 |
国内免费 | 140篇 |
专业分类
化学 | 511篇 |
晶体学 | 21篇 |
力学 | 283篇 |
综合类 | 102篇 |
数学 | 583篇 |
物理学 | 1155篇 |
出版年
2024年 | 1篇 |
2023年 | 16篇 |
2022年 | 31篇 |
2021年 | 53篇 |
2020年 | 45篇 |
2019年 | 35篇 |
2018年 | 51篇 |
2017年 | 73篇 |
2016年 | 100篇 |
2015年 | 74篇 |
2014年 | 95篇 |
2013年 | 149篇 |
2012年 | 87篇 |
2011年 | 129篇 |
2010年 | 105篇 |
2009年 | 125篇 |
2008年 | 145篇 |
2007年 | 160篇 |
2006年 | 171篇 |
2005年 | 149篇 |
2004年 | 122篇 |
2003年 | 102篇 |
2002年 | 97篇 |
2001年 | 75篇 |
2000年 | 65篇 |
1999年 | 53篇 |
1998年 | 50篇 |
1997年 | 42篇 |
1996年 | 38篇 |
1995年 | 35篇 |
1994年 | 33篇 |
1993年 | 21篇 |
1992年 | 17篇 |
1991年 | 23篇 |
1990年 | 18篇 |
1989年 | 13篇 |
1988年 | 14篇 |
1987年 | 8篇 |
1986年 | 12篇 |
1985年 | 8篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1977年 | 2篇 |
1969年 | 1篇 |
1959年 | 2篇 |
排序方式: 共有2655条查询结果,搜索用时 15 毫秒
11.
Inside Cover: Spontaneous Formation of Microgroove Arrays on the Surface of p‐Type Porous Silicon Induced by a Turing Instability in Electrochemical Dissolution (ChemPhysChem 8/2015) 下载免费PDF全文
12.
Amir Hossein Alamdar Mehrdad Pourayoubi Anahid Saneei Michal Duek Monika Ku
erkov Margarida S. Henriques 《Acta Crystallographica. Section C, Structural Chemistry》2015,71(9):824-833
Hirshfeld surfaces and two‐dimensional fingerprint plots are used to analyse the intermolecular interactions in two new phosphorothioic triamide structures, namely N,N′,N′′‐tris(3,4‐dimethylphenyl)phosphorothioic triamide acetonitrile hemisolvate, P(S)[NHC6H3‐3,4‐(CH3)2]3·0.5CH3CN or C24H30N3PS·0.5CH3CN, (I), and N,N′,N′′‐tris(4‐methylphenyl)phosphorothioic triamide–3‐methylpiperidinium chloride (1/1), P(S)[NHC6H4(4‐CH3)]3·[3‐CH3‐C5H9NH2]+·Cl− or C21H24N3PS·C6H14N+·Cl−, (II). The asymmetric unit of (I) consists of two independent phosphorothioic triamide molecules and one acetonitrile solvent molecule, whereas for (II), the asymmetric unit is composed of three components (molecule, cation and anion). In the structure of (I), the different components are organized into a six‐molecule aggregate through N—H...S and N—H...N hydrogen bonds. The components of (II) are aggregated into a two‐dimensional array through N—H...S and N—H...Cl hydrogen bonds. Moreover, interesting features of packing arise in this structure due to the presence of a double hydrogen‐bond acceptor (the S atom of the phosphorothioic triamide molecule) and of a double hydrogen‐bond donor (the N—H unit of the cation). For both (I) and (II), the full fingerprint plot of each component is asymmetric as a consequence of the presence of three fragments. These analyses reveal that H...H interactions [67.7 and 64.3% for the two symmetry‐independent phosphorothioic triamide molecules of (I), 30.7% for the acetonitrile solvent of (I), 63.8% in the phosphorothioic triamide molecule of (II) and 62.9% in the 3‐methylpiperidinium cation of (II)] outnumber the other contacts for all the components in both structures, except for the chloride anion of (II), which only receives the Cl...H contact. The phosphorothioic triamide molecules of both structures include unsaturated C atoms, thus presenting C...H/H...C interactions: 17.6 and 21% for the two symmetry‐independent phosphorothioic triamide molecules in (I), and 22.7% for the phosphorothioic triamide molecule of (II). Furthermore, the N—H...S hydrogen bonds in both (I) and (II), and the N—H...Cl hydrogen bonds in (II), are the most prominent interactions, appearing as large red spots on the Hirshfeld surface maps. The N...H/H...N contacts in structure (I) are considerable, whereas for (II), they give a negligible contribution to the total interactions in the system. 相似文献
13.
《Acta Crystallographica. Section C, Structural Chemistry》2017,73(7):508-516
In the structure of 2‐(4‐chloroanilino)‐1,3,2λ4‐diazaphosphol‐2‐one, C12H11ClN3OP, each molecule is connected with four neighbouring molecules through (N—H)2…O hydrogen bonds. These hydrogen bonds form a tubular arrangement along the [001] direction built from R 33(12) and R 43(14) hydrogen‐bond ring motifs, combined with a C (4) chain motif. The hole constructed in the tubular architecture includes a 12‐atom arrangement (three P, three N, three O and three H atoms) belonging to three adjacent molecules hydrogen bonded to each other. One of the N—H groups of the diazaphosphole ring, not co‐operating in classical hydrogen bonding, takes part in an N—H…π interaction. This interaction occurs within the tubular array and does not change the dimension of the hydrogen‐bond pattern. The energies of the N—H…O and N—H…π hydrogen bonds were studied by NBO (natural bond orbital) analysis, using the experimental hydrogen‐bonded cluster of molecules as the input file for the chemical calculations. In the 1H NMR experiment, the nitrogen‐bound proton of the diazaphosphole ring has a high value of 17.2 Hz for the 2J H–P coupling constant. 相似文献
14.
15.
16.
Christopher Hoffman Douglas Rizzolo Erik Slivken 《Random Structures and Algorithms》2017,50(3):394-419
Permutations that avoid given patterns are among the most classical objects in combinatorics and have strong connections to many fields of mathematics, computer science and biology. In this paper we study the scaling limits of a random permutation avoiding a pattern of length 3 and their relations to Brownian excursion. Exploring this connection to Brownian excursion allows us to strengthen the recent results of Madras and Pehlivan [25] and Miner and Pak [29] as well as to understand many of the interesting phenomena that had previously gone unexplained. © 2016 Wiley Periodicals, Inc. Random Struct. Alg., 50, 394–419, 2017 相似文献
17.
该文提出了一种基于太赫兹时域光谱的水稻种子模式识别方法。实验以10种不同品牌混合掺假的水稻种子为样本,基于采集的样本太赫兹时域光谱数据,通过建立Relief、随机森林(RF)、支持向量机递归特征消除(SVM-RFE)和最大相关最小冗余(mRMR)模型分别对样本光谱波长进行特征选择,最后设计分类器对4种特征选择方法处理后的样本进行分类识别。结果表明,基于布谷鸟算法(CS)优化的极限学习机模型对经RF特征选择算法提取后的样本光谱数据具有最佳识别效果,其准确率可达100%,实验对于法庭科学领域内种子的掺假鉴定具有一定的借鉴意义。 相似文献
18.
Quality assessment of Astragali Radix based on pseudo-targeted metabolomics and chemometric approach
Astragali Radix is widely used because of its dual use in medicine and food, and its quality evaluation is of great importance. In this study, a pseudo-targeted metabolomics approach based on scheduled multiple reaction monitoring was developed, and a total of 114 compounds with good linearity, sensitivity, and reproducibility were selected for relative quantification, and the chemical differences between Astragali Radix of different growth patterns were further compared by chemometric analysis. With the help of multivariate and univariate analysis, 26 differential compounds between wild/semi-wild Astragali Radix and cultivated Astragali Radix were determined. Then five marker compounds were screened out by lasso regression, and further verified by systematic clustering, random forest, support vector machine, and logistic regression. In addition, malonyl-substituted flavonoids showed relatively higher content in wild/semi-wild Astragali Radix. Thus, the malonyl substitution was characteristic for flavonoids in wild/semi-wild Astragali Radix. In conclusion, the application of pseudo-targeted metabolomics and various statistical methods could offer multi-dimensional information for the holistic quality evaluation of Astragali Radix. 相似文献
19.
Dr. Mostofa K. Khan Anas Bsoul Prof. Konrad Walus Dr. Wadood Y. Hamad Prof. Mark J. MacLachlan 《Angewandte Chemie (International ed. in English)》2015,54(14):4304-4308
Chiral nematic mesoporous phenol‐formaldehyde resins, which were prepared using cellulose nanocrystals as a template, can be used as a substrate to produce latent photonic images. These resins undergo swelling, which changes their reflected color. By writing on the films with chemical inks, the density of methylol groups in the resin changes, subsequently affecting their degree of swelling and, consequently, their color. Writing on the films gives latent images that are revealed only upon swelling of the films. Using inkjet printing, it is possible to make higher resolution photonic patterns both as text and images that can be visualized by swelling and erased by drying. This novel approach to printing photonic patterns in resin films may be applied to anti‐counterfeit tags, signage, and decorative applications. 相似文献
20.
基于拓扑描述函数的连续体结构拓扑优化方法 总被引:14,自引:0,他引:14
提出了一种利用拓扑描述函数(TDF)作为拓扑设计变量求解连续体结构拓扑优化问题
的新方法. 优化问题的目标函数是结构的整体柔顺性,约束条件为对于可利用材料的体积限
制. 这种方法不仅可以消除拓扑优化中经常出现的棋盘格式等数值不稳定现象,而且能够有
效地抑制传统算法处理此类优化问题时所引发的边界扩散效应. 与其它的基于水平集描述函
数的拓扑优化方法相比,所提出的算法不仅无需求解控制水平集函数演化的双曲守恒方
程,而且合理地考虑了目标函数的拓扑导数信息,因而使得算法的计算效率有了显著的提高. 相似文献